Kinetics Literature 

Articles théoriques sur la cinétique

1. Sergey Vyazovkin, Alan K. Burnham , Loic Favergeon , Nobuyoshi Koga , Elena Moukhina , Luis A. Pérez-Maqueda , Nicolas Sbirrazzuoli, ICTAC Kinetics Committee recommendations for analysis of multi-step kinetics, Thermochimica Acta, 689, (2020), 178597, https://doi.org/10.1016/j.tca.2020.178597
   
   Les principes de base et les principales recommandations de l'ICTACpour les méthodes"isoconversives" (également connues sous le nom de"model free") et les méthodes"multi-step model fitting" (également connues sous le nom de"model based") à utiliser dans le monde entier sont décrits. L'objectif de ces recommandations est d'aider un non-expert à effectuer efficacement une analyse cinétique multi-étapes et à interpréter ses résultats.
   
2. E.Moukhina, Determination of kinetic mechanisms for reactions measured with thermoanalytical instruments, J.Therm.Anal.Calorim. 109(3) (2012) 1203-1214, doi 10.1007/s10973-012-2406-3
   
   L'article contient les principales règles pour la modélisation cinétique les modèles cinétiques à deux étapes contiennent des étapes de réaction parallèles, consécutives ou compétitives. Les modèles cinétiques à deux étapes sont illustrés par des courbes thermogravimétriques, créées pour le mélange de matériaux de décomposition indépendants (processus indépendants), pour la décomposition en deux étapes d'un matériau (étapes consécutives) et pour la décomposition d'un matériau par deux voies différentes avec le mélange de deux produits dans des concentrations différentes (étapes de réaction concurrentielles)
   
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3. Elena Moukhina, Comparison of isothermal predictions based on model-free and model-based kinetic methods, J.Test.Eval 42(6) (2014) 1377-1386, doi 10.1520/JTE20140145
   
4. Elena Moukhina , Initial kinetic parameters for the model-based kinetic method, High Temperatures-High Pressures, 42 (4) (2013), 287-302
   
5. Elena Moukhina, Direct Analysis in modulated thermogravimetry, Thermochimica Acta, 576 (2014) 75-83, doi 10.1016/j.tca.2013.11.024
   Theory for model free analysis of temperature modulated data.
   
6. J. Opfermann : "Kinetic analysis using multivariate non-linear regression I. Basic concepts" publié dans Journal of Thermal Analysis and Calorimetry, Vol. 60 (2000) 641-658
   
7. I.V.Arkhangelskii et al, Non-isothermal kinetic methods, 2013, ISNB 978-3-8442-4693-3
   FREE DOWNLOAD
   
8. Partie A : M.E. Brown, M. Maciejewski, S. Vyazovkin, R. Nomen, J. Sempere, A. Burnham, J. Opfermann, R. Stey, H.L. Anderson, A. Kemmler, R. Keuleers, J. Janssens, H.O. Desseyn, ChaoRui Li, Tong B. Tang, B. Roduit, J. Malek, T. Mitsuhashi : "Computational aspects of kinetik analysis. Part A : The ICTAC kinetics project-data, methods and results" publié dans Thermochimica Acta 355 (2000) 125-143 doi 10.1016/S0040-6031(00)00443-3
   
9. Partie D : A.K. Burnham : "Computational aspects of kinetic analysis. Part D : The ICTAC kinetics project - multi-thermal-history model-fitting methods and their relation to isoconversional methods" publié dans Thermochimica Acta 355 (2000) 165-170 doi 10.1016/S00406031(00) 00446-9
   
10. D. Hesekamp, M.H. Pahl : "Curing effects on viscosity of reactive epoxy resin adhesives" publié dans Rheologica Acta, Vol. 35, No. 4 (1996)
    
11. Liang Xu : "An introduction to n-th order and autocatalysis reactions".

Quand et pourquoi l'absence de modèle ne suffit pas

1. Méthodes sans modèle, avantages et inconvénients
2. J. Opfermann, E. Kaisersberger, H.J. Flammersheim : "Model-free analysis of thermoanalytical data-advantages and limitations" publié dans Thermochimica Acta 391 (2002) 119-127. Doi 10.1016/S0040-6031(02)00169-7
3. J. Opfermann, H.J. Flammersheim : "Some comments to the paper of J.D. Sewry and M.E. Brown : 'Model-free' kinetic analysis ?" publié dans Thermochimica Acta 397 (2003) 1-3. doi 10.1016/S0040-6031(02)00224-1
4. J. Opfermann, F. Giblin, J. Mayer, E. Kaisersberger : "An improved method for invariant kinetic parameters and a high level of model differentiation" publié dans AMERICAN LABORATORY 1995, -vol. 27, -number 4, -pp. 34-41.

Applications cinétiques in situ

1. Guguschev C., Moukhina E., Wollwebwr J, Dittmar A., In-situ kinetic investigations during aluminium nitride purification and crystal growth processes by capillary coupled mass spectrometry, Thermochimica Acta,526(1) (2011), 213-221, doi 10.1016/j.tca.2011.09.017
2. G.Guguschev, A. Dittmar, E.Moukhina, C.Hartmann, S.Golka, J.Wollweber, M.Bickermann, R.Fornari, Growth of bulk AIN single crystals with low oxygen content taking into account thermal and kinetic effects of oxygen-related gaseous species, Journal of Crystal Growth 360 (2012), doi:10.1016/j.crysgro.2012.02.019

Cinétique en calorimétrie différentielle à balayage (DSC)

1. Claire Strasser, Elena Moukhina, and Jürgen Hartmann , Time-Temperature-Transformation (TTT) Cure Diagram of an Epoxy-Amine System, Macro-Molecular Theory and Simulations, 2024, 2400039.
   
2. Elena Moukhina, Thermal decomposition of AIBN Part C : SADT calculation of AIBN based on DSC experiments, Thermochim. Acta (2015), doi 10.1016/j.tca.2015.06.012
3. Zbynek Plachý , Jonas Uricar , Denis Fros , Anna Prazanova , Karel Dusek, Attila Geczy : "Impact of curing profiles on the Thermo-Mechanical properties of an underfill in Board-Level microelectronic Packaging : Effect on reliability" publié dans Composites : Part A 200 (2026) 109298, doi.org/10.1016/j.compositesa.2025.109298, Accès libre
   
4. F. Spini , I. Marzorati , P. Bettini , A.M. Grande : "Cure kinetics of aromatic disulfide epoxy vitrimer : influence of epoxy/ amine stoichiometry", Thermochimica Acta 753 (2025) 180133,
   doi.org/10.1016/j.tca.2025.180133, doi.org/10.1016/j.tca.2025.180133, Accès libre
   
5. Dio Lins , Steffen Franke, Morten Voß , Jonas Wirries : "Durcissement des adhésifs à basse température dans l'ingénierie du bois : About the relationship between curing kinetics and mechanical properties" publié dans International Journal of Adhesion & Adhesives 134 (2024) 103815, doi.org/10.1016/j.ijadhadh.2024.103815,Accès libre
   
6. H.J. Flammersheim, J. Opfermann : "Kinetic evaluation of DSC curves for reacting systems with variable stoichiometric compositions" publié dans Thermochimica Acta 388 (2002) 389400 doi 10.1016/S0040-6031(02)00042-4
   
7. H.J. Flammersheim, J. Opfermann : "Investigation of Epoxide Curing Reactions by Differential Scanning Calorimetry - Formal Kinetic Evaluation" publié dans Macromolecular Materials and Engineering 286 (2001) 143-150
   
8. H.J. Flammersheim : "Formal-kinetic evaluation of polyaddition reactions - results of a roundrobin test, initialised by the working group 'Polymers' of the German Society for Thermal Analysis (GEFTA)" publié dans Thermochimica Acta 361 (2000) 21-29 doi 10.1016/S00406031(00)00544-X
   
9. H.J. Flammersheim, J. Opfermann : "The dimerization of cyclopentadiene - a test reaction for the kinetic analysis of DSC measurements and the performance of a kinetic evaluation program" publié dans Thermochimica Acta 337 (1999) 149-153 doi 10.1016/S00406031(99)00163-X
   
10. J. Opfermann, W. Hädrich : "Prediction of the thermal response of hazardous materials during storage using an improved technique", publié dans Thermochimica Acta 263 (1995) 29 - 50 doi 10.1016/0040-6031(94)02392-2
    
11. H.J. Flammersheim, J. Opfermann : " Formal kinetic evaluation of reactions with partial diffusion control" publié dans Thermochimica Acta 337 (1999) 141-148 doi 10.1016/S00406031(99)00162-8
    
12. N. Eckardt, H.J. Flammersheim, H.K. Cammenga : "The CIS-Trans Isomerization of Azobenzene in the molten state (The useful test reaction for the kinetic evaluation of DSC measurements)" publié dans Journal of Thermal Analysis and Calorimetry, Vol. 52 (1998) 177
    
13. E. Kaisersberger, J. Opfermann : "Kinetic Evaluation of Exothermal Reactions Measured by DSC" publié dans Thermochimica Acta 187 (1991) 151-158 doi 10.1016/00406031(91)87189-4

Cinétique en thermogravométrie (TGA)

1. Peter R. Hondred, Sungho Yoon, Elena Moukhina, Michael R.Kessler, Degradation of Polyimide Wire Insulation, High Performance Polymers, 23(4) (2011) 335-342,
   doi 10.1177/0954008311409262
   
2. Martin J.G. Fait, Elena Moukhina, Michael Feist, Hans-Joachim Lunk, Thermal decomposition of ammonium paratungstate tetrahydrate : New insights by a combined thermal and kinetic analysis,Thermochim Acta(2016),
   doi:10.1016/j.tca.2016.05.009
   
3. Elena Moukhina, How to simulate and optimise debinding processes, Materials World magazine
   
4. Ashwini K, Resmi R, Muneer Parayangat , Mohamed Abbas : Thermogravimetric analysis of Limonia Acidissima shell for thermal-kinetic properties and thermodynamic characteristics, publié dans South African Journal of Chemical Engineering 54 (2025) 133-147, doi.org/10.1016/j.sajce.2025.07.012, accès libre
   
5. Naienne da Silva Santana , Sergio Neves Monteiro , Tatiana Carestiato da Silva et Michelle Gonçalves Mothé : Article Investigation and Determination of Kinetic Parameters of Sweeteners Based on Steviol Glycosides by Isoconversional Methods, publié dans Foods 2025, 14, 1233, doi.org/10.3390/foods14071233, Accès libre
   
6. Szymon Szufa, Grzegorz Wielgosinski, Piotr Piersa, Justyna Czerwinska, Maria Dzikuc, Łukasz Adrian, Wiktoria Lewandowska et Marta Marczak : "Torrefaction of Straw from Oats and Maize for Use as a Fuel and Additive to Organic Fertilizers-TGA Analysis, Kinetics as Products for Agricultural Purposes" publié dans Energies 2020, 13, 2064 ;
   doi.org/10.3390/en13082064,Accès libre
   
7. Nebojša Manić, Bojan Janković & Vladimir Dodevski, Model-free and model-based kinetic analysis of Poplar fluff (Populus alba) pyrolysis process under dynamic conditions. J. Therm. Anal. Calorim. (2020).
   doi.org/10.1007/s10973-020-09675-y.
   
8. Sergio Cordova, Kevin Estala-Rodriguez, EvgenyShafirovich, Oxidation kinetics of magnesium particles determined by isothermal and non-isothermal methods of thermogravimetric analysis , Combustion and Flame (2022)
   
9. Yuming Wen, Ilman Nuran Zaini, Shule Wang ,Wangzhong Mu, Pär Göran Jönsson, Weihong Yang, Synergistic effect of the co-pyrolysis of cardboard and polyethylene : A kinetic and thermodynamic study. Energy (2021),
   https://doi.org/10.1016/j.energy.2021.120693
   
10. Yuming Wen, ZiyiShi, Shule Wang, Wangzhong Mu, Pär Göran Jönsson, Weihong Yang, Pyrolysis of raw and anaerobically digested organic fractions of municipal solid waste : Kinetics, thermodynamics, and product characterization. Chemical Engineering Journal (2021) https://doi.org/10.1016/j.cej.2021.129064
    
11. Shule Wang, Yuming Wena, Henry Hammarström, Pär Göran Jönsson, Weihong Yang, Pyrolysis behaviour, kinetics and thermodynamic data of hydrothermal carbonization-Treated pulp and paper mill sludge, Renewable Energy (2021) https://doi.org/10.1016/j.renene.2021.06.027
    
12. Shule Wang, Yuming Wen, Ziyi Shi, Lukasz Niedzwiecki, Marcin Baranowski, Michał Czerep, Wangzhong Mu, Halina Pawlak Kruczek, Pär Göran Jönsson, Weihong Yang, Effect of hydrothermal carbonization pretreatment on the pyrolysis behavior of the digestate of agricultural waste : A view on kinetics and thermodynamics. Chemical Engineering Journal (2022) https://doi.org/10.1016/j.cej.2021.133881
    
13. Aluisio A. Cabral, Jose M. Rivas-Mercury, Jose R.M. Sucupira, Miguel A. Rodríguez, Antonio H. De Aza, Pilar Pena, Elena Moukhina. Effect of the milling conditions on the decomposition kinetics of gibbsite publié dans Boletín de la Sociedad Española de Cerámica y Vidrio, février 2023. DOI : 10.1016/j.bsecv.2023.02.003
    
14. Md Delwar Hossain, Swapan Saha Md Kamrul Hassan, Anthony Chun Yin Yuen, Cheng Wang, Establishing pyrolysis kinetics for fire modelling and thermal analysis of polymeric cladding materials used in high-rise buildings. Case Studies in Construction Materials 19 (2023) e02535.
    https://doi.org/10.1016/j.cscm.2023.e02535
    
15. Md Delwar Hossain, Md Kamrul Hassan, Swapan Saha, Anthony Chun Yin Yuen, Cheng Wang, Laurel George et Richard Wuhrer, Thermal and Pyrolysis Kinetics Analysis of Glass Wool and XPS Insulation Materials Used in High-Rise Buildings. Fire 2023, 6, 231
    https://doi.org/10.3390/fire6060231

Cinétique en spectrométrie de masse (SM)

Martin J.G. Fait, Elena Moukhina, Michael Feist, Hans-Joachim Lunk, Thermal decomposition of ammonium paratungstate tetrahydrate : New insights by a combined thermal and kinetic analysis,Thermochim Acta(2016),
doi:10.1016/j.tca.2016.05.009

Cinétique en dilatométrie (DIL)

1. J. Opfermann, J. Blumm, W.D. Emmerich : "Simulation of the sintering behavior of a ceramic green body using advanced thermokinetic analysis" publié dans Thermochimica Acta 318 (1998) 213-220 doi 10.1016/S0040-6031(98)00345-1
   
2. J. Blumm, J. Opfermann, U. Janosovits, H.J. Pohlmann "Simulation of the Sintering Behavior of High-Tech Ceramics by Means of Dilatometry and Thermokinetic Analysis" publié dans High Temperatures - High Pressures, 32(5):567-572 Janvier 2000, DOI : 10.1068/htwu521

Matériaux hautement énergétiques

1. Elena Moukhina, Thermal decomposition of AIBN Part C : SADT calculation of AIBN based on DSC experiments, Thermochim. Acta (2015), doi 10.1016/j.tca.2015.06.012

2. alexander G. Harter, Thomas M. Klapötke, Jasmin T. Lechner, Jörg Stierstorfer, Kinetic Predictions Concerning the Long-Term Stability of TKX-50 and Other Common Explosives Using the NETZSCH Kinetics Neo Software. Publié dans Propellants, Explosives, Pyrotechnics, Volume 47, Issue 7, July 2022,doi.