Kinetics Literature
動力学に関する理論的記事
- Sergey Vyazovkin, Alan K. Burnham , Loic Favergeon , 古賀信義 , Elena Moukhina , Luis A. Pérez-Maqueda , Nicolas Sbirrazzuoli, ICTAC Kinetics Committee recommendations for analysis of multi-step kinetics, Thermochimica Acta, 689, (2020), 178597, https://doi.org/10.1016/j.tca.2020.178597
ICTACから、世界的に使用されている「等変換」(「モデルフリー」とも呼ばれる)手法と「多段階モデル適合」(「モデルベース」とも呼ばれる)手法の基本原則と主な推奨事項が記載されている。これらの推奨事項の目的は、非専門家が多段階速度論解析を効率的に実施し、その結果を解釈するのに役立つことである。 - E.Moukhina, Determination of kinetic mechanism for reactions measured with thermoanalytical instruments, J.Therm.Anal.Calorim.109(3) (2012) 1203-1214, doi 10.1007/s10973-012-2406-3
この論文には以下の内容が含まれている。 動力学モデリングの主なルール 並列、連続、競合反応ステップを含む独立した分解材料の混合物(独立プロセス)、1つの材料の二段階分解(連続ステップ)、異なる濃度の2つの生成物の混合物(競合反応ステップ)による2つの異なる方法での1つの材料の分解(競合反応ステップ)について作成された熱重量曲線を用いて、二段階速度論モデルを説明する
無料ダウンロード - Elena Moukhina, model-free and model-based kinetic methods based of isothermal predictions comparison of isothermal predictions based on model-free and model-based kinetic methods, J.Test.Eval 42(6) (2014) 1377-1386, doi 10.1520/JTE20140145
- Elena Moukhina , Model-based kinetic method の初期動力学パラメータ, High Temperatures-High Pressures, 42 (4) (2013), 287-302
- Elena Moukhina, Direct Analysis in Modulated Thermogravimetry, Thermochimica Acta, 576 (2014) 75-83, doi 10.1016/j.tca.2013.11.024
Theory for model free analysis of temperature modulated data. - J.Opfermann: "Kinetic analysis using multivariate non-linear regression I. Basic concepts" Journal of Thermal Analysis and Calorimetry, Vol. 60 (2000) 641-658
掲載。 - I.V.Arkhangelskii et al., Non-isothermal kinetic methods, 2013, ISNB 978-3-8442-4693-3
無料ダウンロード - パートA:M.E. Brown, M. Maciejewski, S. Vyazovkin, R. Nomen, J. Sempere, A. Burnham, J. Opfermann, R. Stey, H.L. Anderson, A. Kemmler, R. Keuleers, J. Jans, R. Sty.Keuleers, J. Janssens, H.O. Desseyn, ChaoRui Li, Tong B. Tang, B. Roduit, J. Malek, T. Mitsuhashi: "Computational aspects of kinetik analysis.Part A: The ICTAC kinetics project-data, methods and results" Thermochimica Acta 355 (2000) 125-143 doi 10.1016/S0040-6031(00)00443-3
に掲載。 - Part D: A.K. Burnham: "Computational aspects of kinetic analysis.パートD:The ICTAC kinetics project - multi-thermal-history model-fitting methods and their relation to isoconversional methods" Thermochimica Acta 355 (2000) 165-170 doi 10.1016/S00406031(00) 00446-9
に掲載。 - D.Hesekamp, M.H. Pahl: "Curing effects on viscosity of reactive epoxy resin adhesives" Rheologica Acta, Vol. 35, No. 4 (1996)
に掲載。 - Liang Xu:"n次反応と自己触媒反応の紹介".
モデル・フリーでは不十分なときと理由
- モデル・フリー法の利点と欠点
- J.Opfermann, E. Kaisersberger, H.J. Flammersheim: "Model-free analysis of thermoanalytical data-advantages and limitations" Thermochimica Acta 391 (2002) 119-127 に掲載。Doi 10.1016/S0040-6031(02)00169-7
- J.J. Opfermann, H.J. Flammersheim: "Some comments to the paper of J.D. Sewry and M.E. Brown: 'Model-free' kinetic analysis?" Thermochimica Acta 397 (2003) 1-3 に掲載。
- J.Opfermann、F. Giblin、J. Mayer、E. Kaisersberger: "An improved method for invariant kinetic parameters and a high level of model differentiation" AMERICAN LABORATORY 1995, -vol.27, -number 4, -pp.34-41.
インサイチュ・キネティック・アプリケーション
- Guguschev C., Moukhina E., Wollwebwr J, Dittmar A., In-situ kinetic investigations during aluminium nitride purification and crystal growth processes by capillary coupled mass spectrometry, Thermochimica Acta,526(1) (2011), 213-221, doi 10.1016/j.tca.2011.09.017
- G.Guguschev、A.Dittmar、E.Moukhina、C.Hartmann、S.Golka、J.Wollweber、M.Bickermann、R.Fornari、酸素関連ガス種の熱的・動力学的効果を考慮した低酸素含有バルクAIN単結晶の成長、結晶成長学会誌360(2012)、di:10.1016/j.crysgro.2012.02.019
示差走査熱量測定(DSC)におけるカイネティクス
- Claire Strasser, Elena Moukhina, and Jürgen Hartmann , Time-Temperature-Transformation (TTT) Cure Diagram of an Epoxy-Amine System, Macro-Molecular Theory and Simulations, 2024, 2400039.
- Elena Moukhina, AIBNの熱分解 Part C: SADT calculation of AIBN based on DSC experiments, Thermochim.Acta (2015), doi 10.1016/j.tca.2015.06.012
- Zbynek Plachý , Jonas Uricar , Denis Fros , Anna Prazanova , Karel Dusek, Attila Geczy: "Impact of curing profiles on the Thermo-Mechanical properties of an underfill in Board-Level microelectronic Packaging:Effect on reliability" が Composites 誌に掲載された:Part A 200 (2026) 109298,doi.org/10.1016/j.compositesa.2025.109298、 オープンアクセス
- F.スピニ、I.マルゾラティ、P.ベッティーニ、A.M.グランデ:「Cure kinetics of aromatic disulfide epoxy vitrimer: influence of epoxy/ amine stoichiometry", Thermochimica Acta 753 (2025) 180133,
doi.org/10.1016/j.tca.2025.180133, doi.org/10.1016/j.tca.2025.180133、オープンアクセス - Dio Lins, Steffen Franke, Morten Voß, Jonas Wirries : 「木材工学における低温接着剤硬化:International Journal of Adhesion & Adhesives 134 (2024) 103815,doi.org/10.1016/j.ijadhadh.2024.103815に掲載されました、オープンアクセス
- H.J. Flammersheim, J. Opfermann: "Kinetic evaluation of DSC curves for reacting systems with variable stoichiometric compositions" 掲載 Thermochimica Acta 388 (2002) 389400 doi 10.1016/S0040-6031(02)00042-4
- H.J. Flammersheim, J. Opfermann: "Investigation of Epoxide Curing Reactions by Differential Scanning Calorimetry - Formal Kinetic Evaluation" Macromolecular Materials and Engineering 286 (2001) 143-150
に掲載。 - H.J. Flammersheim: "Formal-kinetic evaluation of polyaddition reactions - results of a roundrobin test, initialised by the working group 'Polymers' of the German Society for Thermal Analysis (GEFTA)" 掲載 Thermochimica Acta 361 (2000) 21-29 doi 10.1016/S00406031(00)00544-X
- H.J. Flammersheim, J. Opfermann: "The dimerization of cyclopentadiene - a test reaction for the kinetic analysis of DSC measurements and the performance of a kinetic evaluation program" presented in Thermochimica Acta 337 (1999) 149-153 doi 10.1016/S00406031(99)00163-X
- J.Opfermann, W. Hädrich: "Prediction of the thermal response of hazardous materials during storage using an improved technique", published in Thermochimica Acta 263 (1995) 29 - 50 doi 10.1016/0040-6031(94)02392-2
- H.J. Flammersheim, J. Opfermann: " Formal kinetic evaluation of reactions with partial diffusion control" Thermochimica Acta 337 (1999) 141-148 doi 10.1016/S00406031(99)00162-8
に掲載。 - N.Eckardt, H.J. Flammersheim, H.K. Cammenga: "The CIS-Trans Isomerization of Azobenzene in molten state (The useful test reaction for the kinetic evaluation of DSC measurements)" Journal of Thermal Analysis and Calorimetry, Vol. 52 (1998) 177
に掲載。 - E.Kaisersberger, J. Opfermann: "Kinetic Evaluation of Exothermal Reactions Measured by DSC" Thermochimica Acta 187 (1991) 151-158 doi 10.1016/00406031(91)87189-4 に掲載。
熱重量測定(TGA)におけるカイネティクス
- Peter R. Hondred, Sungho Yoon, Elena Moukhina, Michael R.Kessler, Degradation of Polyimide Wire Insulation, High Performance Polymers, 23(4) (2011) 335-342,
doi 10.1177/0954008311409262 - Martin J.G. Fait, Elena Moukhina, Michael Feist, Hans-Joachim Lunk, パラタングステン酸アンモニウム四水和物の熱分解:New insights by a combined thermal and kinetic analysis,Thermochim Acta(2016),
doi:10.1016/j.tca.2016.05.009 - Elena Moukhina, How to simulate and optimise debinding processes, Materials World magazine
- Ashwini K, Resmi R, Muneer Parayangat , Mohamed Abbas:リモニアアシディシマ殻の熱重量分析による熱運動特性と熱力学特性、South African Journal of Chemical Engineering 54 (2025) 133-147,doi.org/10.1016/j.sajce.2025.07.012に掲載、オープンアクセス
- Naienne da Silva Santana , Sergio Neves Monteiro , Tatiana Carestiato da Silva and Michelle Gonçalves Mothé: Article Investigation and Determination of Kinetic Parameters of Sweeteners Based on Steviol Glycosides by Isoconversional Methods, Foods 2025, 14, 1233,doi.org/10.3390/foods14071233掲載、 オープンアクセス
- Szymon Szufa, Grzegorz Wielgosinski, Piotr Piersa, Justyna Czerwinska, Maria Dzikuc, Łukasz Adrian, Wiktoria Lewandowska and Marta Marczak: "Torrefaction of Straw from Oats and Maize for Use as a Fuel and Additive to Organic Fertilizers-TGA Analysis, Kinetics as Products for Agricultural Purposes" Energies 2020, 13, 2064;
doi.org/10.3390/en13082064,オープンアクセス - Nebojša Manić, Bojan Janković & Vladimir Dodevski, 動的条件下におけるポプラ綿毛(Populus alba)熱分解プロセスのモデルフリーおよびモデルベースの動力学解析.J. Therm.Anal.Calorim.(2020).
doi.org/10.1007/s10973-020-09675-y. - Sergio Cordova, Kevin Estala-Rodriguez, EvgenyShafirovich, Oxidation kinetics of magnesium particles determined by isothermal and non-isothermal methods of thermogravimetric analysis , Combustion and Flame (2022)
- 楊偉宏, 段ボールとポリエチレンの共熱分解の相乗効果:A kinetic and thermodynamic study.Energy (2021),
https://doi.org/10.1016/j.energy.2021.120693 - Yuming Wen, ZiyiShi, Shule Wang, Wangzhong Mu, Pär Göran Jönsson, Weihong Yang, Pyrolysis of raw and anaerobically digested organic fractions of municipal solid waste:Kinetics, Thermodynamics, and product characterization.Chemical Engineering Journal (2021) https://doi.org/10.1016/j.cej.2021.129064
- Shule Wang, Yuming Wena, Henry Hammarström, Pär Göran Jönsson, Weihong Yang, Hydrothermal Carbonization-Treated pulp and paper mill sludge, Renewable Energy (2021) https://doi.org/10.1016/j.renene.2021.06.027
. - Shule Wang, Yuming Wen, Ziyi Shi, Lukasz Niedzwiecki, Marcin Baranowski, Michał Czerep, Wangzhong Mu, Halina Pawlak Kruczek, Pär Göran Jönsson, Weihong Yang, Effect of hydrothermal carbonization pretreatment on the pyrolysis behavior of the digestate of agricultural waste:楊偉宏, 水熱炭化前処理が農業廃棄物消化液の熱分解挙動に及ぼす影響:動力学と熱力学の観点から.化学工学ジャーナル (2022) https://doi.org/10.1016/j.cej.2021.133881
- Aluisio A. Cabral, Jose M. Rivas-Mercury, Jose R.M. Sucupira, Miguel A. Rodríguez, Antonio H. De Aza, Pilar Pena, Elena Moukhina.Effect of the milling conditions on the decomposition kinetics of gibbsite published in Boletín de la Sociedad Española de Cerámica y Vidrio, February 2023.DOI: 10.1016/j.bsecv.2023.02.003
- Md Delwar Hossain, Swapan Saha Md Kamrul Hassan, Anthony Chun Yin Yuen, Cheng Wang, 高層ビルで使用される高分子クラッド材の火災モデリングと熱解析のための熱分解カイネティクスの確立。Case Studies in Construction Materials 19 (2023) e02535.
https://doi.org/10.1016/j.cscm.2023.e02535
. - Md Delwar Hossain, Md Kamrul Hassan, Swapan Saha, Anthony Chun Yin Yuen, Cheng Wang, Laurel George and Richard Wuhrer, 高層ビルで使用されるグラスウールおよび XPS 断熱材の熱および熱分解カイネティクス解析。火災 2023, 6, 231
https://doi.org/10.3390/fire6060231
ダイラトメトリーにおけるカイネティクス(DIL)
- J.Opfermann, J. Blumm, W.D. Emmerich: "Simulation of sintering behavior of a ceramic green body using advanced thermokinetic analysis" 掲載 Thermochimica Acta 318 (1998) 213-220 doi 10.1016/S0040-6031(98)00345-1
- J.Blumm, J. Opfermann, U. Janosovits, H.J. Pohlmann "Simulation of the Sintering Behavior of High-Tech Ceramics by Means of Dilatometry and Thermokinetic Analysis" 掲載:High Temperatures - High Pressures, 32(5):567-572 January 2000, DOI: 10.1068/htwu521
