Kinetics Literature 

Artículos teóricos sobre cinética

1. Sergey Vyazovkin, Alan K. Burnham , Loic Favergeon , Nobuyoshi Koga , Elena Moukhina , Luis A. Pérez-Maqueda , Nicolas Sbirrazzuoli, ICTAC Kinetics Committee recommendations for analysis of multi-step kinetics, Thermochimica Acta, 689, (2020), 178597, https://doi.org/10.1016/j.tca.2020.178597
   
   Se describen los principios básicos y las principales recomendaciones del ICTACpara los métodos"isoconversionales" (también conocidos como"sin modelo") y los métodos de"ajuste de modelos multipaso" (también conocidos como"basados en modelos") que se utilizan en todo el mundo. El objetivo de estas recomendaciones es ayudar a los no expertos a realizar eficazmente análisis cinéticos multipaso y a interpretar sus resultados.
   
2. E.Moukhina, Determinación de mecanismos cinéticos para reacciones medidas con instrumentos termoanalíticos, J.Therm.Anal.Calorim. 109(3) (2012) 1203-1214, doi 10.1007/s10973-012-2406-3
   
   El artículo contiene las principales reglas para la modelización cinética que contengan etapas de reacción paralelas, consecutivas o competitivas. Los modelos cinéticos de dos pasos se ilustran mediante curvas termogravimétricas, creadas para la mezcla de materiales en descomposición independientes (procesos independientes), para la descomposición en dos pasos de un material (pasos consecutivos) y para la descomposición de un material por dos vías diferentes con la mezcla de dos productos en diferentes concentraciones (pasos de reacción competitivos)
   
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3. Elena Moukhina, Comparison of isothermal predictions based on model-free and model-based kinetic methods, J.Test.Eval 42(6) (2014) 1377-1386, doi 10.1520/JTE20140145
   
4. Elena Moukhina , Parámetros cinéticos iniciales para el método cinético basado en modelos, High Temperatures-High Pressures, 42 (4) (2013), 287-302
   
5. Elena Moukhina, Análisis directo en termogravimetría modulada, Thermochimica Acta, 576 (2014) 75-83, doi 10.1016/j.tca.2013.11.024
   Teoría para el análisis sin modelos de datos de temperatura modulada.
   
6. J. Opfermann: "Kinetic analysis using multivariate non-linear regression I. Basic concepts" publicado en Journal of Thermal Analysis and Calorimetry, Vol. 60 (2000) 641-658
   
7. I.V.Arkhangelskii et al., Non-isothermal kinetic methods, 2013, ISNB 978-3-8442-4693-3
   DESCARGA GRATUITA
   
8. Parte A: M.E. Brown, M. Maciejewski, S. Vyazovkin, R. Nomen, J. Sempere, A. Burnham, J. Opfermann, R. Stey, H.L. Anderson, A. Kemmler, R. Keuleers, J. Janssens, H.O. Desseyn, ChaoRui Li, Tong B. Tang, B. Roduit, J. Malek, T. Mitsuhashi: "Computational aspects of kinetik analysis. Part A: The ICTAC kinetics project-data, methods and results" publicado en Thermochimica Acta 355 (2000) 125-143 doi 10.1016/S0040-6031(00)00443-3
   
9. Parte D: A.K. Burnham: "Computational aspects of kinetic analysis. Parte D: The ICTAC kinetics project - multi-thermal-history model-fitting methods and their relation to isoconversional methods" publicado en Thermochimica Acta 355 (2000) 165-170 doi 10.1016/S00406031(00) 00446-9
   
10. D. Hesekamp, M.H. Pahl: "Curing effects on viscosity of reactive epoxy resin adhesives" publicado en Rheologica Acta, Vol. 35, No. 4 (1996)
    
11. Liang Xu: "Una introducción a las reacciones de orden n-ésimo y autocatálisis".

Cuándo y por qué la ausencia de modelo no es suficiente

1. Métodos sin modelo, ventajas e inconvenientes
2. J. Opfermann, E. Kaisersberger, H.J. Flammersheim: "Model-free analysis of thermoanalytical data-advantages and limitations" publicado en Thermochimica Acta 391 (2002) 119-127. Doi 10.1016/S0040-6031(02)00169-7
3. J. Opfermann, H.J. Flammersheim: "Some comments to the paper of J.D. Sewry and M.E. Brown: 'Model-free' kinetic analysis?" publicado en Thermochimica Acta 397 (2003) 1-3. doi 10.1016/S0040-6031(02)00224-1
4. J. Opfermann, F. Giblin, J. Mayer, E. Kaisersberger: "An improved method for invariant kinetic parameters and a high level of model differentiation" publicado en AMERICAN LABORATORY 1995, -vol. 27, -number 4, -pp. 34-41.

Aplicaciones cinéticas in situ

1. Guguschev C., Moukhina E., Wollwebwr J, Dittmar A., In-situ kinetic investigations during aluminium nitride purification and crystal growth processes by capillary coupled mass spectrometry, Thermochimica Acta,526(1) (2011), 213-221, doi 10.1016/j.tca.2011.09.017
2. G.Guguschev, A. Dittmar, E.Moukhina, C.Hartmann, S.Golka, J.Wollweber, M.Bickermann, R.Fornari, Growth of bulk AIN single crystals with low oxygen content taking into account thermal and kinetic effects of oxygen-related gaseous species, Journal of Crystal Growth 360 (2012), doi:10.1016/j.crysgro.2012.02.019

Cinética en Calorimetría Diferencial de Barrido (DSC)

1. Claire Strasser, Elena Moukhina, and Jürgen Hartmann , Time-Temperature-Transformation (TTT) Cure Diagram of an Epoxy-Amine System, Macro-Molecular Theory and Simulations, 2024, 2400039.
   
2. Elena Moukhina, Thermal decomposition of AIBN Part C: SADT calculation of AIBN based on DSC experiments, Thermochim. Acta (2015), doi 10.1016/j.tca.2015.06.012
3. Zbynek Plachý , Jonas Uricar , Denis Fros , Anna Prazanova , Karel Dusek, Attila Geczy: "Impact of curing profiles on the Thermo-Mechanical properties of an underfill in Board-Level microelectronic Packaging: Effect on reliability" publicado en Composites: Part A 200 (2026) 109298, doi.org/10.1016/j.compositesa.2025.109298, Acceso abierto
   
4. F. Spini , I. Marzorati , P. Bettini , A.M. Grande: "Cure kinetics of aromatic disulfide epoxy vitrimer: influence of epoxy/ amine stoichiometry", Thermochimica Acta 753 (2025) 180133,
   doi.org/10.1016/j.tca.2025.180133, doi.org/10.1016/j.tca.2025.180133, Acceso libre
   
5. Dio Lins , Steffen Franke, Morten Voß , Jonas Wirries : "Curado de adhesivos a baja temperatura en ingeniería de la madera: Acerca de la relación entre la cinética de curado y las propiedades mecánicas" publicado en International Journal of Adhesion & Adhesives 134 (2024) 103815, doi.org/10.1016/j.ijadhadh.2024.103815,Acceso libre
   
6. H.J. Flammersheim, J. Opfermann: "Kinetic evaluation of DSC curves for reacting systems with variable stoichiometric compositions" publicado en Thermochimica Acta 388 (2002) 389400 doi 10.1016/S0040-6031(02)00042-4
   
7. H.J. Flammersheim, J. Opfermann: "Investigation of Epoxide Curing Reactions by Differential Scanning Calorimetry - Formal Kinetic Evaluation" publicado en Macromolecular Materials and Engineering 286 (2001) 143-150
   
8. H.J. Flammersheim: "Formal-kinetic evaluation of polyaddition reactions - results of a roundrobin test, initialised by the working group 'Polymers' of the German Society for Thermal Analysis (GEFTA)" publicado en Thermochimica Acta 361 (2000) 21-29 doi 10.1016/S00406031(00)00544-X
   
9. H.J. Flammersheim, J. Opfermann: "The dimerization of cyclopentadiene - a test reaction for the kinetic analysis of DSC measurements and the performance of a kinetic evaluation program" publicado en Thermochimica Acta 337 (1999) 149-153 doi 10.1016/S00406031(99)00163-X
   
10. J. Opfermann, W. Hädrich: "Prediction of the thermal response of hazardous materials during storage using an improved technique", publicado en Thermochimica Acta 263 (1995) 29 - 50 doi 10.1016/0040-6031(94)02392-2
    
11. H.J. Flammersheim, J. Opfermann: " Formal kinetic evaluation of reactions with partial diffusion control" publicado en Thermochimica Acta 337 (1999) 141-148 doi 10.1016/S00406031(99)00162-8
    
12. N. Eckardt, H.J. Flammersheim, H.K. Cammenga: "The CIS-Trans Isomerization of Azobenzene in the molten state (The useful test reaction for the kinetic evaluation of DSC measurements)" publicado en Journal of Thermal Analysis and Calorimetry, Vol. 52 (1998) 177
    
13. E. Kaisersberger, J. Opfermann: "Kinetic Evaluation of Exothermal Reactions Measured by DSC" publicado en Thermochimica Acta 187 (1991) 151-158 doi 10.1016/00406031(91)87189-4

Cinética en Termogravometría (TGA)

1. Peter R. Hondred, Sungho Yoon, Elena Moukhina, Michael R.Kessler, Degradation of Polyimide Wire Insulation, High Performance Polymers, 23(4) (2011) 335-342,
   doi 10.1177/0954008311409262
   
2. Martin J.G. Fait, Elena Moukhina, Michael Feist, Hans-Joachim Lunk, Thermal decomposition of ammonium paratungstate tetrahydrate: New insights by a combined thermal and kinetic analysis,Thermochim Acta(2016),
   doi:10.1016/j.tca.2016.05.009
   
3. Elena Moukhina, How to simulate and optimise debinding processes, revista Materials World
   
4. Ashwini K, Resmi R, Muneer Parayangat , Mohamed Abbas: Thermogravimetric analysis of Limonia Acidissima shell for thermal-kinetic properties and thermodynamic characteristics, publicado en South African Journal of Chemical Engineering 54 (2025) 133-147, doi.org/10.1016/j.sajce.2025.07.012, acceso libre
   
5. Naienne da Silva Santana , Sergio Neves Monteiro , Tatiana Carestiato da Silva y Michelle Gonçalves Mothé: Article Investigation and Determination of Kinetic Parameters of Sweeteners Based on Steviol Glycosides by Isoconversional Methods, publicado en Foods 2025, 14, 1233, doi.org/10.3390/foods14071233, Acceso libre
   
6. Szymon Szufa, Grzegorz Wielgosinski, Piotr Piersa, Justyna Czerwinska, Maria Dzikuc, Łukasz Adrian, Wiktoria Lewandowska y Marta Marczak: "Torrefaction of Straw from Oats and Maize for Use as a Fuel and Additive to Organic Fertilizers-TGA Analysis, Kinetics as Products for Agricultural Purposes" publicado en Energies 2020, 13, 2064;
   doi.org/10.3390/en13082064,Acceso libre
   
7. Nebojša Manić, Bojan Janković & Vladimir Dodevski, Model-free and model-based kinetic analysis of Poplar fluff (Populus alba) pyrolysis process under dynamic conditions. J. Therm. Anal. Calorim. (2020).
   doi.org/10.1007/s10973-020-09675-y.
   
8. Sergio Cordova, Kevin Estala-Rodriguez, EvgenyShafirovich, Cinética de oxidación de partículas de magnesio determinada por métodos isotérmicos y no isotérmicos de análisis termogravimétrico , Combustion and Flame (2022)
   
9. Yuming Wen, Ilman Nuran Zaini, Shule Wang ,Wangzhong Mu, Pär Göran Jönsson, Weihong Yang, Synergistic effect of the co-pyrolysis of cardboard and polyethylene: A kinetic and thermodynamic study. Energy (2021),
   https://doi.org/10.1016/j.energy.2021.120693
   
10. Yuming Wen, ZiyiShi, Shule Wang, Wangzhong Mu, Pär Göran Jönsson, Weihong Yang, Pyrolysis of raw and anaerobically digested organic fractions of municipal solid waste: Kinetics, thermodynamics, and product characterization. Chemical Engineering Journal (2021) https://doi.org/10.1016/j.cej.2021.129064
    
11. Shule Wang, Yuming Wena, Henry Hammarström, Pär Göran Jönsson, Weihong Yang, Pyrolysis behaviour, kinetics and thermodynamic data of hydrothermal carbonization-Treated pulp and paper mill sludge, Renewable Energy (2021) https://doi.org/10.1016/j.renene.2021.06.027
    
12. Shule Wang, Yuming Wen, Ziyi Shi, Lukasz Niedzwiecki, Marcin Baranowski, Michał Czerep, Wangzhong Mu, Halina Pawlak Kruczek, Pär Göran Jönsson, Weihong Yang, Effect of hydrothermal carbonization pretreatment on the pyrolysis behavior of the digestate of agricultural waste: A view on kinetics and thermodynamics. Chemical Engineering Journal (2022) https://doi.org/10.1016/j.cej.2021.133881
    
13. Aluisio A. Cabral, Jose M. Rivas-Mercury, Jose R.M. Sucupira, Miguel A. Rodríguez, Antonio H. De Aza, Pilar Pena, Elena Moukhina. Effect of the milling conditions on the decomposition kinetics of gibbsite publicado en Boletín de la Sociedad Española de Cerámica y Vidrio, febrero 2023. DOI: 10.1016/j.bsecv.2023.02.003
    
14. Md Delwar Hossain, Swapan Saha Md Kamrul Hassan, Anthony Chun Yin Yuen, Cheng Wang, Establishing pyrolysis kinetics for fire modelling and thermal analysis of polymeric cladding materials used in high-rise buildings. Case Studies in Construction Materials 19 (2023) e02535.
    https://doi.org/10.1016/j.cscm.2023.e02535
    
15. Md Delwar Hossain, Md Kamrul Hassan, Swapan Saha, Anthony Chun Yin Yuen, Cheng Wang, Laurel George y Richard Wuhrer, Thermal and Pyrolysis Kinetics Analysis of Glass Wool and XPS Insulation Materials Used in High-Rise Buildings. Fuego 2023, 6, 231
    https://doi.org/10.3390/fire6060231

Cinética en espectrometría de masas (EM)

Martin J.G. Fait, Elena Moukhina, Michael Feist, Hans-Joachim Lunk, Thermal decomposition of ammonium paratungstate tetrahydrate: New insights by a combined thermal and kinetic analysis,Thermochim Acta(2016),
doi:10.1016/j.tca.2016.05.009

Cinética en Dilatometría (DIL)

1. J. Opfermann, J. Blumm, W.D. Emmerich: "Simulation of the sintering behavior of a ceramic green body using advanced thermokinetic analysis" publicado en Thermochimica Acta 318 (1998) 213-220 doi 10.1016/S0040-6031(98)00345-1
   
2. J. Blumm, J. Opfermann, U. Janosovits, H.J. Pohlmann "Simulation of the Sintering Behavior of High-Tech Ceramics by Means of Dilatometry and Thermokinetic Analysis" publicado en High Temperatures - High Pressures, 32(5):567-572 enero 2000, DOI: 10.1068/htwu521

Materiales altamente energéticos

1. Elena Moukhina, Thermal decomposition of AIBN Part C: SADT calculation of AIBN based on DSC experiments, Thermochim. Acta (2015), doi 10.1016/j.tca.2015.06.012

2. alexander G. Harter, Thomas M. Klapötke, Jasmin T. Lechner, Jörg Stierstorfer, Kinetic Predictions Concerning the Long-Term Stability of TKX-50 and Other Common Explosives Using the NETZSCH Kinetics Neo Software. Publicado en Propellants, Explosives, Pyrotechnics,Volume 47, Issue 7, July 2022,doi.