Kinetics Neo

Kinetics Literature 

Contents

Theoretical Articles about Kinetics

When and Why Model-Free Is Not Enough

In-Situ Kinetic Applications

Kinetics in Differential Scanning Calorimetry (DSC)

Kinetics In Thermogravometry (TGA)

Kinetics in Mass-Spectrometry (MS)

Kinetics in Dilatometry (DIL) 

High Energetic Materials

Theoretical Articles about Kinetics

  1. Sergey Vyazovkin, Alan K. Burnham , Loic Favergeon , Nobuyoshi Koga , Elena Moukhina , Luis A. Pérez-Maqueda , Nicolas Sbirrazzuoli, ICTAC Kinetics Committee recommendations for analysis of multi-step kinetics, Thermochimica Acta, 689, (2020), 178597, https://doi.org/10.1016/j.tca.2020.178597

    Basic principles and main recommendations from ICTACfor "isoconversional" (also known as "model free") methods and "multi-step model fitting" (also known as "model based") methods to be used worldwide are described. The objective of these recommendations is to help a non-expert with efficiently performing multi-step kinetic analysis and interpreting its results.
     
  2. E.Moukhina, Determination of kinetic mechanisms for reactions measured with thermoanalytical instruments, J.Therm.Anal.Calorim. 109(3) (2012) 1203-1214, doi 10.1007/s10973-012-2406-3

    The article contains main rules for kinetic modelling containing parallel, consecutive or competitive reaction steps. Two-step kinetic models are illustrated by thermogravimetric curves, created for the mixture of independent decomposing materials (independent processes), for double- step decomposition of one material (consecutive steps) and for decomposition of one material by two different ways with the mixture of two products in different concentrations (competitive reaction steps)

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  3. Elena Moukhina, Comparison of isothermal predictions based on model-free and model-based kinetic methods, J.Test.Eval 42(6) (2014) 1377-1386, doi 10.1520/JTE20140145
     
  4. Elena Moukhina , Initial kinetic parameters for the model-based kinetic method, High Temperatures-High Pressures, 42 (4) (2013), 287-302
     
  5. Elena Moukhina, Direct Analysis in modulated thermogravimetry, Thermochimica Acta, 576 (2014) 75-83, doi 10.1016/j.tca.2013.11.024
    Theory for model free analysis of temperature modulated data.
     
  6. J. Opfermann: "Kinetic analysis using multivariate non-linear regression I. Basic concepts" published in Journal of Thermal Analysis and Calorimetry, Vol. 60 (2000) 641-658
     
  7. I.V.Arkhangelskii et al., Non-isothermal kinetic methods, 2013, ISNB 978-3-8442-4693-3 
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  8. Part A:   M.E. Brown, M. Maciejewski, S. Vyazovkin, R. Nomen, J. Sempere, A. Burnham, J. Opfermann, R. Stey, H.L. Anderson, A. Kemmler, R. Keuleers, J. Janssens, H.O. Desseyn, ChaoRui Li, Tong B. Tang, B. Roduit, J. Malek, T. Mitsuhashi: "Computational aspects of kinetik analysis. Part A: The ICTAC kinetics project-data, methods and results" published in Thermochimica Acta 355 (2000) 125-143  doi 10.1016/S0040-6031(00)00443-3
     
  9. Part D:   A.K. Burnham: "Computational aspects of kinetic analysis. Part D: The ICTAC kinetics project - multi-thermal-history model-fitting methods and their relation to isoconversional methods" published in Thermochimica Acta 355 (2000) 165-170 doi 10.1016/S00406031(00)00446-9  
     
  10. D. Hesekamp, M.H. Pahl: "Curing effects on viscosity of reactive epoxy resin adhesives" published in Rheologica Acta, Vol. 35, No. 4 (1996)
     
  11. Liang Xu: "An introduction to n-th order and autocatalysis reactions".

When and Why Model-Free Is Not Enough

  1. Model-Free Methods, Advantages and Disadvantages
  2. J. Opfermann, E. Kaisersberger, H.J. Flammersheim: "Model-free analysis of thermoanalytical data-advantages and limitations" published in Thermochimica Acta 391 (2002) 119-127. Doi 10.1016/S0040-6031(02)00169-7
  3. J. Opfermann, H.J. Flammersheim: "Some comments to the paper of J.D. Sewry and M.E. Brown: 'Model-free' kinetic analysis?" published in Thermochimica Acta 397 (2003) 1-3. doi 10.1016/S0040-6031(02)00224-1
  4. J. Opfermann, F. Giblin, J. Mayer, E. Kaisersberger: "An improved method for invariant kinetic parameters and a high level of model differentiation" published in AMERICAN LABORATORY 1995, -vol. 27, -number 4, -pp. 34-41.

In-Situ Kinetic Applications

  1. Guguschev C., Moukhina E., Wollwebwr J, Dittmar A., In-situ kinetic investigations during aluminium nitride purification and crystal growth processes by capillary coupled mass spectrometry, Thermochimica Acta,526(1) (2011), 213-221, doi 10.1016/j.tca.2011.09.017
  2. G.Guguschev, A. Dittmar, E.Moukhina, C.Hartmann, S.Golka, J.Wollweber, M.Bickermann, R.Fornari, Growth of bulk AIN single crystals with low oxygen content taking into account thermal and kinetic effects of oxygen-related gaseous species, Journal of Crystal Growth 360 (2012), doi:10.1016/j.crysgro.2012.02.019

Kinetics in Differential Scanning Calorimetry (DSC)

  1. Claire Strasser, Elena Moukhina, and Jürgen Hartmann , Time–Temperature-Transformation (TTT) Cure Diagram of an Epoxy–Amine System, Macro-Molecular Theory and Simulations, 2024, 2400039.
     
  2. Elena Moukhina, Thermal decomposition of AIBN Part C: SADT calculation of AIBN based on DSC experiments, Thermochim. Acta (2015), doi 10.1016/j.tca.2015.06.012
  3. Zbynek Plachý , Jonas Uricar , Denis Fros , Anna Prazanova , Karel Dusek, Attila Geczy: “Impact of curing profiles on the Thermo-Mechanical properties of an underfill in Board-Level microelectronic Packaging: Effect on reliability” published in Composites: Part A 200 (2026) 109298, doi.org/10.1016/j.compositesa.2025.109298, Open Access
     
  4. F. Spini , I. Marzorati , P. Bettini , A.M. Grande: “Cure kinetics of aromatic disulfide epoxy vitrimer: influence of epoxy/ amine stoichiometry”, Thermochimica Acta 753 (2025) 180133, 
    doi.org/10.1016/j.tca.2025.180133, doi.org/10.1016/j.tca.2025.180133, Open Access
     
  5. Dio Lins , Steffen Franke, Morten Voß , Jonas Wirries : “Low-temperature adhesive curing in timber engineering: About the relationship between curing kinetics and mechanical properties”  published in International Journal of Adhesion & Adhesives 134 (2024) 103815, doi.org/10.1016/j.ijadhadh.2024.103815,  Open Access
     
  6. H.J. Flammersheim, J. Opfermann: "Kinetic evaluation of DSC curves for reacting systems with variable stoichiometric compositions" published in Thermochimica Acta 388 (2002) 389400 doi 10.1016/S0040-6031(02)00042-4  
     
  7. H.J. Flammersheim, J. Opfermann: "Investigation of Epoxide Curing Reactions by Differential Scanning Calorimetry - Formal Kinetic Evaluation" published in Macromolecular Materials and Engineering 286 (2001) 143-150
     
  8. H.J. Flammersheim: "Formal-kinetic evaluation of polyaddition reactions - results of a roundrobin test, initialised by the working group 'Polymers' of the German Society for Thermal Analysis (GEFTA)" published in Thermochimica Acta 361 (2000) 21-29 doi 10.1016/S00406031(00)00544-X  
     
  9. H.J. Flammersheim, J. Opfermann: "The dimerization of cyclopentadiene - a test reaction for the kinetic analysis of DSC measurements and the performance of a kinetic evaluation program" published in Thermochimica Acta 337 (1999) 149-153 doi 10.1016/S00406031(99)00163-X  
     
  10. J. Opfermann, W. Hädrich: "Prediction of the thermal response of hazardous materials during storage using an improved technique", published in Thermochimica Acta 263 (1995) 29 - 50  doi 10.1016/0040-6031(94)02392-2
     
  11. H.J. Flammersheim, J. Opfermann: " Formal kinetic evaluation of reactions with partial diffusion control" published in Thermochimica Acta 337 (1999) 141-148 doi 10.1016/S00406031(99)00162-8
     
  12. N. Eckardt, H.J. Flammersheim, H.K. Cammenga: "The CIS-Trans Isomerization of Azobenzene in the molten state (The useful test reaction for the kinetic evaluation of DSC measurements)" published in Journal of Thermal Analysis and Calorimetry, Vol. 52 (1998) 177
     
  13. E. Kaisersberger, J. Opfermann: "Kinetic Evaluation of Exothermal Reactions Measured by DSC" published in Thermochimica Acta 187 (1991) 151-158  doi 10.1016/00406031(91)87189-4

Kinetics In Thermogravometry (TGA)

  1. Peter R. Hondred, Sungho Yoon, Elena Moukhina, Michael R.Kessler, Degradation of Polyimide Wire Insulation, High Performance Polymers, 23(4) (2011) 335-342,
    doi 10.1177/0954008311409262
     
  2. Martin J.G. Fait, Elena Moukhina, Michael Feist, Hans-Joachim Lunk, Thermal decomposition of ammonium paratungstate tetrahydrate: New insights by a combined thermal and kinetic analysis,Thermochim Acta(2016),
    doi:10.1016/j.tca.2016.05.009
     
  3. Elena Moukhina, How to simulate and optimise debinding processes, Materials World magazine 
     
  4. Ashwini K, Resmi R, Muneer Parayangat , Mohamed Abbas: Thermogravimetric analysis of Limonia Acidissima shell for thermal-kinetic properties and thermodynamic characteristics, published in South African Journal of Chemical Engineering 54 (2025) 133–147, doi.org/10.1016/j.sajce.2025.07.012,  Open Access
     
  5. Naienne da Silva Santana , Sergio Neves Monteiro , Tatiana Carestiato da Silva and Michelle Gonçalves Mothé: Article Investigation and Determination of Kinetic Parameters of Sweeteners Based on Steviol Glycosides by Isoconversional Methods, published in Foods 2025, 14, 1233, doi.org/10.3390/foods14071233, Open Access
     
  6. Szymon Szufa, Grzegorz Wielgosinski, Piotr Piersa, Justyna Czerwinska, Maria Dzikuc, Łukasz Adrian, Wiktoria Lewandowska and Marta Marczak: “Torrefaction of Straw from Oats and Maize for Use as a Fuel and Additive to Organic Fertilizers—TGA Analysis, Kinetics as Products for Agricultural Purposes” published in Energies 2020, 13, 2064; 
    doi.org/10.3390/en13082064,Open Access
     
  7. Nebojša Manić, Bojan Janković & Vladimir Dodevski, Model-free and model-based kinetic analysis of Poplar fluff (Populus alba) pyrolysis process under dynamic conditions. J. Therm. Anal. Calorim. (2020). 
    doi.org/10.1007/s10973-020-09675-y.
     
  8. Sergio Cordova, Kevin Estala-Rodriguez, EvgenyShafirovich, Oxidation kinetics of magnesium particles determined by isothermal and non-isothermal methods of thermogravimetric analysis , Combustion and Flame (2022)
     
  9. Yuming Wen, Ilman Nuran Zaini, Shule Wang ,Wangzhong Mu, Pär Göran Jönsson, Weihong Yang, Synergistic effect of the co-pyrolysis of cardboard and polyethylene: A kinetic and thermodynamic study. Energy (2021),
    https://doi.org/10.1016/j.energy.2021.120693
     
  10. Yuming Wen, ZiyiShi, Shule Wang, Wangzhong Mu, Pär Göran Jönsson, Weihong Yang, Pyrolysis of raw and anaerobically digested organic fractions of municipal solid waste: Kinetics, thermodynamics, and product characterization. Chemical Engineering Journal (2021) https://doi.org/10.1016/j.cej.2021.129064
     
  11. Shule Wang, Yuming Wena, Henry Hammarström, Pär Göran Jönsson, Weihong Yang, Pyrolysis behaviour, kinetics and thermodynamic data of hydrothermal carbonization–Treated pulp and paper mill sludge, Renewable Energy (2021) https://doi.org/10.1016/j.renene.2021.06.027
     
  12. Shule Wang, Yuming Wen, Ziyi Shi, Lukasz Niedzwiecki, Marcin Baranowski, Michał Czerep, Wangzhong Mu, Halina Pawlak Kruczek, Pär Göran Jönsson, Weihong Yang, Effect of hydrothermal carbonization pretreatment on the pyrolysis behavior of the digestate of agricultural waste: A view on kinetics and thermodynamics. Chemical Engineering Journal (2022) https://doi.org/10.1016/j.cej.2021.133881
     
  13. Aluisio A. Cabral, Jose M. Rivas-Mercury, Jose R.M. Sucupira, Miguel A. Rodríguez, Antonio H. De Aza, Pilar Pena, Elena Moukhina. Effect of the milling conditions on the decomposition kinetics of gibbsite published in Boletín de la Sociedad Española de Cerámica y Vidrio, February 2023. DOI: 10.1016/j.bsecv.2023.02.003
     
  14. Md Delwar Hossain, Swapan Saha Md Kamrul Hassan, Anthony Chun Yin Yuen, Cheng Wang, Establishing pyrolysis kinetics for fire modelling and thermal analysis of polymeric cladding materials used in high-rise buildings. Case Studies in Construction Materials 19 (2023) e02535.
    https://doi.org/10.1016/j.cscm.2023.e02535
     
  15. Md Delwar Hossain, Md Kamrul Hassan, Swapan Saha, Anthony Chun Yin Yuen, Cheng Wang, Laurel George and Richard Wuhrer, Thermal and Pyrolysis Kinetics Analysis of Glass Wool and XPS Insulation Materials Used in High-Rise Buildings. Fire 2023, 6, 231
    https://doi.org/10.3390/fire6060231

Kinetics in Mass-Spectrometry (MS)

Martin J.G. Fait, Elena Moukhina, Michael Feist, Hans-Joachim Lunk, Thermal decomposition of ammonium paratungstate tetrahydrate: New insights by a combined thermal and kinetic analysis,Thermochim Acta(2016),
doi:10.1016/j.tca.2016.05.009

Kinetics in Dilatometry (DIL) 

  1. J. Opfermann, J. Blumm, W.D. Emmerich: "Simulation of the sintering behavior of a ceramic green body using advanced thermokinetic analysis" published in Thermochimica Acta 318 (1998) 213-220 doi 10.1016/S0040-6031(98)00345-1
     
  2. J. Blumm, J. Opfermann, U. Janosovits, H.J. Pohlmann "Simulation of the Sintering Behavior of High-Tech Ceramics by Means of Dilatometry and Thermokinetic Analysis" published in High Temperatures - High Pressures, 32(5):567-572 January 2000, DOI: 10.1068/htwu521

High Energetic Materials

1. Elena Moukhina, Thermal decomposition of AIBN Part C: SADT calculation of AIBN based on DSC experiments, Thermochim. Acta (2015), doi 10.1016/j.tca.2015.06.012

2.  Alexander G. Harter, Thomas M. Klapötke, Jasmin T. Lechner, Jörg Stierstorfer, Kinetic Predictions Concerning the Long-Term Stability of TKX-50 and Other Common Explosives Using the NETZSCH Kinetics Neo Software. Published in Propellants, Explosives, Pyrotechnics,Volume 47, Issue 7, July 2022,doi.

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